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Author(s): 

Hassan Hala. M.

Issue Info: 
  • Year: 

    2023
  • Volume: 

    7
  • Issue: 

    11
  • Pages: 

    853-870
Measures: 
  • Citations: 

    0
  • Views: 

    33
  • Downloads: 

    73
Abstract: 

This study aims to evaluate the efficacy of compounds as corrosion inhibitors for stainless steel in hydrochloric acid solution using gravimetric technique and electrochemical measurements. Stainless steel is resistant to corrosion and rust due to its chromium content, which reacts with oxygen in the air to form a protective coating. Passivation is the process of creating a thin layer of chrome oxide when exposed to oxygen, preventing rust. In this investigation, corrosion inhibitors made from benzoic acid derivatives were applied to 316 stainless steel in a 0.5 M hydrochloric acid solution. The outermost parts of the investigated stainless steel samples were examined using scanning electron microscopy and energy dispersive spectroscopy. The study also assessed the fundamental properties of the studied inhibitors using the dynamic molecular simulation method. The best inhibitor concentration for C3 at 291 K was 1.0 102 M, resulting in the highest inhibition efficiency (88%).In light of the concentrations of the antagonists under research and the impact of ambient the temperature, the current research investigates the efficacy of inhibition. The best inhibitor concentration for C3 at 291 K was 1.0 102 M, and this resulted in the highest inhibition efficiency (88%).

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Issue Info: 
  • Year: 

    2018
  • Volume: 

    6
  • Issue: 

    1
  • Pages: 

    14-20
Measures: 
  • Citations: 

    0
  • Views: 

    202
  • Downloads: 

    102
Abstract: 

In the past, damaged tissue was removed from the patient's body. But now tissue regeneration using scaffolds and implants are used to repair the damaged tissue and organs. Besides the mechanical properties of metallic biomaterials, they suffer from bioinertness. Using some surface treatment techniques, the bioactivity and also corrosion resistance of titanium implants could be improved. In this study, the effect of H2O2 and alkali treatments on the corrosion behavior of titanium implant in the artificial saliva, surface morphology and phases formed on the surface, was investigated using electrochemical corrosion test, scanning electron microscopy (SEM) and thin film x-ray diffractometry (TF-XRD), respectively. The results indicated that on the surface of H2O2 and alkali treated titanium samples, fine particles of anatase and fine wires of rutile were formed, respectively. The results revealed that the corrosion resistance of alkali treated titanium in the artificial saliva was higher than that of the H2O2 treated titanium sample. The corrosion current density for the untreated, H2O2 and alkali treated titanium samples was about 0. 6×10-8, 5×10-8, 3×10-8A/cm2, respectively.

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Issue Info: 
  • Year: 

    2012
  • Volume: 

    21
  • Issue: 

    12
  • Pages: 

    837-844
Measures: 
  • Citations: 

    0
  • Views: 

    339
  • Downloads: 

    0
Keywords: 
Abstract: 

Effect of incorporating SiAlON nanoparticles at different loading levels (0–12 wt%) on chemical resistance of epoxy coating was investigated by immersion in basic (Na2CO3، pH=11) and salty (NaCl 3.5 wt%) (environments at 85 °C for 60 days. Epoxy resin chemical resistant coating grade based on bisphenol A was used with polyamine hardener as a curing agent. In these testes، surface morphology changes of the samples were studied and compared owing to initiation and propagation of cracks. Results indicate an enhancement in the epoxy nano composite chemical resistance due to the addition of small fraction of SiAlON nanoparticles. Samples containing 3 and 5 wt% of SiAlON nano powders were considered as optimum samples compared to all the other samples، because they showed more resistances to initiation and propagation of cracks and lower permeability in chemical environment in comparison with neat resin and other samples. Also، epoxy coatings containing SiAlON nanoparticles were successfully coated on steel substrates and corrosion electrochemical behavior of these nano composite coatings were characterized by electrochemical impedance spectroscopy (EIS). The electrochemical monitoring of the coated steel over 35 days of immersion in 3.5 wt% NaCl solution at room temperature suggested the positive role of nanoparticles in improving the corrosion resistance of the coated steel.

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Issue Info: 
  • Year: 

    2016
  • Volume: 

    19
Measures: 
  • Views: 

    176
  • Downloads: 

    89
Keywords: 
Abstract: 

IN THIS WORK, TWO QUANTUM MECHANICAL DESCRIPTORS WERE PROPOSED FOR QUANTITATIVE STRUCTUREINHIBITION  RELATIONSHIP (QSIR) STUDY OF COPPER CORROSIONIN SULFURIC ACID MEDIA. THESE DESCRIPTORS WERE CHOSEN BASED ON INHIBITION MECHANISM OF SOME BENZENETHIOL DERIVATIVES ON COPPER CORROSION. THE FIRST DESCRIPTOR WAS ADSORPTION ENERGY OF INHIBITOR COMPOUNDSON COPPER CLUSTER (EADS) AND THE SECOND WAS EXCRETION ENERGY OF H3O+ ION BYCOPPER-INHIBITOR COMPLEX SYSTEM (EEXC). ...

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Issue Info: 
  • Year: 

    2024
  • Volume: 

    13
  • Issue: 

    50
  • Pages: 

    41-56
Measures: 
  • Citations: 

    1
  • Views: 

    42
  • Downloads: 

    0
Abstract: 

Human activities, such as production and consumption, generate waste that pollutes environment. This pollution creates unfavorable conditions for humans and other living beings.  Microorganisms, however, offer potential solutions. These tiny can be both beneficial and harmful to humans. While their negative aspects, like pathogenicity or corrosion, have been exclusively studied, this review focuses on the positive potential of these often-threatened bacteria. Here, we explore their ability to clean and biodegrade environmental pollutants. The review draws on research conducted by the authors and other researchers, examining how bacteria responsible for corrosion can biodegrade and purify various pollutants such as PCP, pesticides, detergents, and even bioplastics. Since the biodegradation pathways for these pollutants have been identified and their safety for living organisms considered, the use of such bacteria for environmental cleaning is recommended.

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Issue Info: 
  • Year: 

    1384
  • Volume: 

    3
Measures: 
  • Views: 

    947
  • Downloads: 

    0
Abstract: 

در صنعت مقابله پیشگیرانه با خطرات احتمالی باعث افزایش کارایی و افزایش تولید در یک واحد تولیدی می گردد. مدیریت خوردگی بعنوان بخشی از سیستم مدیریتی یکپارچه در ارتباط با توسعه، اجرا، بازبینی و نگهداری از مسایل خوردگی می باشد. برنامه ای در سیستم مدیریتی موفق و کارآمد خواهد بود که بتواند با دیگر اجزا سیستم ارتباط منطقی برقرار نماید. در این مورد مدیریت خوردگی باید بتواند داده های خود را به دیگر برنامه های مدیریتی در سیستم مدیریت جامع القا نماید و از طرف دیگر داده های آنها را به بهترین نحو ممکن مورد استفاده قرار دهد. همچنین سیستمهای مدیریتی به ابزار قابل اطمینانی برای پیش بینی حوادث احتمالی آینده و محاسبه فاکتورهای لازم برای مدیریت نیاز دارند. از مهمترین ابزارهایی که می توان بوسیله آن داده های مطمئنی بدست آورد ارزیابی ریسک حوادث احتمالی می باشد. در مدیریت خوردگی بر پایه ریسک نیز محاسبات لازم برای اقدامات کنترلی و بازرسی ها بر اساس ریسکی است که همراه با هر یک از وقایع احتمالی خوردگی وجود دارد. در روشهای مدیریتی بر پایه ریسک نیز تمرکز اقدامات بر روی نقاط پر خطر و با ریسک بالا خواهد بود. بر این اساس نقاط بحرانی توسط روشهای مختلف ارزیابی ریسک مشخص شده و با بکارگیری از روشهای مناسب مانیتورینگ خوردگی و نیز با تدوین برنامه هایی جهت بازرسی و اقدامات کنترلی و تعمیراتی که در آینده طرح ریزی خواهند شد این نقاط را مدنظر قرار می دهند. با توجه به میزان خسارات ناشی از خطرات احتمالی، مدیریت ریسک تنها یک گزینه آلترناتیو محسوب نشده بلکه بکارگیری آن در هر تشکیلاتی از الزامات مدیریتی می باشد. در صورتیکه در یک سیستم تمامی محاسبات بر اساس ریسک حاصل از حوادث و اقدامات بعدی و کنترل ریسکها باشد می توان به یک سیستم مدیریت جامع بر پایه ریسک دست یافت که در حال حاضر بسیاری از صنایع در کشورهای پیشرفته و رو به توسعه بر این اساس مدیریت می شوند.

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Writer: 

ABUTALEBI S.

Issue Info: 
  • Year: 

    2013
  • Volume: 

    16
Measures: 
  • Views: 

    115
  • Downloads: 

    89
Abstract: 

INTRODUCTION: CORROSION PROTECTION OF STAINLESS STEEL HAS BEEN THE SUBJECT OF STUDY OF MANY CORROSION SCIENTISTS.THE USE OF CORROSION INHIBITOR IS ONE OF THE MOST EFFECTIVE MEASURES FOR PROTECTING METAL SURFACES AGAINST CORROSION IN ACID ENVIRONMENTS [1]. MANY HETEROCYCLIC COMPOUNDS CONTAINING HETEROATOMS LIKE N, O, S HAVE BEEN REPORTED TO BE EFFECTIVE INHIBITORS FOR THE CORROSION OF STEEL IN ACID MEDIA BY SEVERAL AUTHORS [2, 3].THE INHIBITION EFFICIENCY OF THESE INHIBITORS IS REPORTEDLY CONNECTED TO THE FORMATION OF A LAYER ON THE METAL SURFACE THROUGH ADSORPTION LEADING TO BLOCKAGE OF ACTIVE SITES. THE INHIBITION PROPERTY OF THESE COMPOUNDS IS ATTRIBUTED TO THEIR MOLECULAR STRUCTURE. THE PLANARITY AND THE LONE ELECTRON PAIRS IN THE HETEROATOMS ARE IMPORTANT FEATURES THAT DETERMINE THE ADSORPTION OF THESE MOLECULES ON THE METALLIC SURFACE. THE EFFECT OF THE MOLECULAR STRUCTURE ON THE CHEMICAL REACTIVITY HAS BEEN OBJECT OF GREAT INTEREST IN SEVERAL DISCIPLINES OF CHEMISTRY.

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Issue Info: 
  • Year: 

    2016
  • Volume: 

    18
Measures: 
  • Views: 

    113
  • Downloads: 

    88
Keywords: 
Abstract: 

CORROSION IS A SERIOUS ENVIRONMENTAL PROBLEM IN THE OIL, FERTILIZER, METALLURGICAL AND OTHER INDUSTRIES. INHIBITORS ARE ONE OF THE PRACTICAL MEANS OF PREVENTING CORROSION. INHIBITORS ARE COMPOUNDS THAT REDUCE THE RATE OF CORROSION BY ABSORBED ON THE METAL SURFACES. ...

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Issue Info: 
  • Year: 

    2013
  • Volume: 

    1
  • Issue: 

    1
  • Pages: 

    1-14
Measures: 
  • Citations: 

    0
  • Views: 

    1060
  • Downloads: 

    0
Abstract: 

Corrosion cast study is one of the procedures for studying the structure of the blood vessels in a particular tissue or organ. In the present study, the circulatory system of Silver Carp was studied by using four different methods of resin injection. 12 fish with a weight range of 850 -1000 g were obtained from a commercial fish farm. The Fish were anesthetized using a solution of 5% benzocain in 96% ethanol and injected intraperitoneally with heparin (4000 IU/kg). After 40 min, the fish were killed using an overdose of the benzocain solution, and then, fluid artificial resin made on the basis of methylmetacrylate was injected through the caudal artery, bulbus arteriosus, and dorsal and ventral aortas. The Fish were submerged for 24-48 hours in a bath water at room temperature until the polymerization and hardening of methylmetacrylate. Then, they were placed in a 25% KOH solution for 24-48 hours to obtain a maceration of the organic tissue. In this study, various parts of the heart and its vessels, gill vessels, gastric vein, portal vein, hepatic vein, dorsal aorta and its branches, renal and caudal arteries and related smaller vessels were also determined. Overall, it seems that the injection of resin via bulbus arteriosus of the heart was the best and most effective method for the corrosion cast study of the circulatory system in Silver Carp.

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Writer: 

Abutalebi Kh.

Issue Info: 
  • Year: 

    2013
  • Volume: 

    16
Measures: 
  • Views: 

    120
  • Downloads: 

    75
Abstract: 

INTRODUCTION: CORROSION INHIBITORS ARE ONE OF THE MOST EFFECTIVE ALTERNATIVES FOR THE PROTECTION OF METALLIC SURFACES AGAINST CORROSION. MANY HETEROCYCLIC COMPOUNDS CONTAINING NITROGEN, SULFUR, AND OXYGEN ATOMS ARE EFFICIENT INHIBITORS OF CORROSION FOR COPPER IN ACIDIC MEDIA [1]. THE CORROSION INHIBITION EFFICIENCY OF VARIOUS THIADIAZOLE COMPOUNDS HAS BEEN INVESTIGATED EXPERIMENTALLY BY SEVERAL RESEARCHERS [2, 3].QUANTUM CHEMICAL CALCULATIONS HAVE BEEN USED RECENTLY TO EXPLAIN THE MECHANISM OF CORROSION INHIBITION AND PROVED TO BE A VERY POWERFUL TOOL FOR STUDYING THE MECHANISM. THE PROPERTY OF CORROSION INHIBITION OF ORGANIC COMPOUNDS IS RELATED TO THEIR MOLECULAR STRUCTURE. THE MOLECULAR STRUCTURE, INCLUDING THE ELECTRONIC PARAMETERS, CAN BE OBTAINED BY MEANS OF THE THEORETICAL CALCULATIONS BY USING THE COMPUTATIONAL METHODOLOGIES OF QUANTUM CHEMISTRY [4]. IN THE PRESENT STUDY, THE INHIBITION EFFECTS OF THREE AMINO THIADIAZOLES, NAMELY 2-AMINO-5-PHENYL-1, 3, 4-THIADIAZOLE (APT), 2-AMINO-5- (4-METHOXYPHENYL) -1, 3, 4-THIADIAZOLE (AMPT) AND 2-AMINO-5- (4-NITROPHENYL) -1, 3, 4-THIADIAZOLE (ANPT) HAVE BEEN INVESTIGATED COMPUTATIONALLY USING DFT AT B3LYP/6-31G* LEVEL OF THEORY. ALSO THE RELATIONSHIP BETWEEN CALCULATED QUANTUM CHEMICAL PARAMETERS SUCH AS THE ENERGIES OF HIGHEST OCCUPIED MOLECULAR ORBITAL (EHOMO) AND THE LOWEST UNOCCUPIED MOLECULAR ORBITAL (ELUMO), THE ENERGY DIFFERENCE (DE) BETWEEN EHOMO AND ELUMO, DIPOLE MOMENT (M) AND EXPERIMENTAL INHIBITION EFFICIENCIES OF THE INHIBITORS WAS DISCUSSED.

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